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Recent Publications


Primary nucleation in metastable solutions of poly(3-hexylthiophene)

Tianyu Wu, Sivasurender Chandran, Yao Zhang, Tianze Zheng, Thomas Pfohl, Jun Xu, Günter Reiter. Macromolecules 55 (2022) 3325–3334

2022-tianyu.jpgDue to its smallness and low probability of formation, the determination of the size of the critical primary nucleus represents a great challenge in polymer crystallization. We are still missing a feasible approach providing experimental access to primary nucleation. In this work, we investigated the dependence of the incubation time on the degree of supersaturation for a well-defined metastable regime of a prototypical conjugated polymer, i.e., poly(3-hexylthiophene). Based on Kashchiev’s nucleation theorem and verified by a simulation model for primary nucleation based on the kinetics of attaching and detaching crystalline units, we deduced the number of crystalline units within the critical nucleus  [more...]



Illumination of Conjugated Polymers Reduces Nucleation Probability and Slows Down Crystal Growth Rate

Yaser AlShetwi, Brahim Bessif, Michael Sommer, Günter Reiter. Macromolecules 54, 2021, 11478–11485

2021-rei--14.jpgUsing the set-up of an optical microscope, we have examined the influence of illumination with white light on the crystallization behavior in molten films of poly(3-(2,5-dioctylphenyl)thiophene) and poly(3-hexylthiophene). We observed a reduction in nucleation density and crystal growth rate induced by illumination. The amount of this reduction increased with the increase in light intensity. Melting samples previously crystallized under illumination and recrystallizing them in the dark showed full reversibility of the crystallization behavior, demonstrating that these changes in the crystallization behavior induced by illumination were not permanent. (mehr...)



Semi-crystalline poly(thioether) prepared by visible-light-induced organocatalyzed thiol-ene polymerization in emulsion.

Cuong Minh Quoc Le, Gautier Schrodj, Ibrahima Ndao, Brahim Bessif, Barbara Heck, Thomas Pfohl, Günter Reiter, Justine Elgoyen, Radmila Tomovaska and Abraham Chemtob. Macromol. Rapid Commun. 2021, 2100740

2021-rei-15.jpgA photocatalytic thiol-ene aqueous emulsion polymerization under visible-light is described to prepare linear semicrystalline latexes using 2,2’-dimercaptodiethyl sulfide as dithiol and various dienes. The procedure involves low irradiance (3 mW cm–2), LED irradiation source, eosin-Y disodium as organocatalyst, low catalyst loading (< 0.05% mol) and short reaction time scales (< 1 h). The resulting latexes has molecular weights of about 10 kg mol–1, average diameters of 100 nm and a linear structure consisting only of thioether repeating units. (more...)


 

List of Publications

High-throughput injection molding of transparent fused silica glass
Markus Mader, Oliver Schlatter, Barbara Heck, Andreas Warmbold, Alex Dorn, Hans Zappe, Patrick Risch, Dorothea Helmer, Frederik Kotz, Bastian E. Rapp. Science 372 (2021) 182-186
Formation of large polymer crystals from metastable solutions
Tianyu Wu. Inauguraldissertation der Fakultät für Chemie und Pharmazie 2020, DOI: 10.6094/UNIFR/167415
Exploring pathways to equilibrate Langmuir polymer films
Abhijna Das, Sebastian Noack, Helmut Schlaad, Günter Reiter, Renate Reiter. Langmuir 36 (2020) 8184–8192
Energy transport and light propagation mechanisms in organic single crystals
Bernd Wittmann, Stephan Wiesneth, Sajedeh Motamen, Laurent Simon, Françoise Serein-Spirau, Günter Reiter, and Richard Hildner. Journal of Chemical Physics 153 (2020) 144202
Large quantum efficiency enhancements of pristine conjugated polymer MEH-PPV by interlayer polymer diffusion
Po-Tsun Chen, Ya-Wei Yang, Günter Reiter, Arnold C.-M. Yang. Polymer 204 (2020) 122753
Formation of Needle-like Poly(3-hexylthiophene) Crystals from Metastable Solutions
Tianyu Wu, Thomas Pfohl, Sivasurender Chandran, Michael Sommer and Günter Reiter. Macromolecules 53 (2020) 8303–8312
Rheological Properties of Blends of Isotactic Polystyrene–Isotactic Poly(para-methylstyrene) Films Derived from a Comparative Dewetting Study
Austine Amukayia Mulama, Konstantinos Roumpos, Pradipkanti Lairenjam, Andrew Oduor, Günter Reiter. Macromolecules 53 (2020) 9122–9130
Dewetting-Induced Alignment and Ordering of Cylindrical Mesophases in Thin Block Copolymer Films
Heng Zhang, Binghua Wang, Gang Wang, Changyu Shen, Jingbo Chen, Günter Reiter, Bin Zhang. Macromolecules 53, (2020) 9631–9640
Estimation of the Size of Critical Secondary Nuclei of Melt-Grown Poly(l-lactide) Lamellar Crystals
Shujing Zhang, Baohua Guo, Günter Reiter, Jun Xu. Macromolecules 53 (2020) 3482–3492
Translating molecular relaxations in non-equilibrated polymer melts into lifting macroscopic loads
Farzad Ramezani, Jörg Baschnagel, and Günter Reiter. Phys. Rev. Materials 4 (2020) 082601
A new growth process for crystalline ultra-thin layers of conjugated oligomers used in field-effect transistor applications
Sven Renkert, Sadiara Fall, Sajedeh Motamen, Thibaut Jarrosson, Françoise Serein-Spirau, Thomas Heiser, Laurent Simon, Günter Reiter, Jean-Luc Bubendorff. Applied Surface Science 539 (2021) 148024
The memorizing capacity of polymers
Günter Reiter. J. Chem. Phys. 152, 150901 (2020)
Formation of asymmetric leaf-shaped crystals in ultrathin films of oriented polyethylene molecules resulting from high-temperature relaxation and recrystallization
Huihui Li, Duanzijing Liu, Xinyun Bu, Zhenzhen Zhou, Zhongjie Ren, Xiaoli Sun, Renate Reiter, Shouke Yan, Günter Reiter. Macromolecules 53 (2020) 346-354
Controlling phase transitions in Langmuir polymer films
Abhijna Das. Inauguraldissertation der Fakultät für Mathematik und Physik 2020. DOI: 10.6094/UNIFR/167266
Controlling Nucleation in Quasi-Two-Dimensional Langmuir Poly(L-lactide) Films through Variation of the Rate of Compression
Abhijna Das, Ahmed S. El-Tawargy, Emna Khechine, Sebastian Noack, Helmut Schlaad, Günter Reiter, and Renate Reiter. Langmuir 35 (2019) 6129-6136
Activity of the Gramicidin A Ion Channel in a Lipid Membrane with Switchable Physical Properties
Renate Reiter, Ekaterina Zaitseva, Gerhard Baaken, Ibrahim Halimeh, Jan C. Behrends, Andreas Zumbuehl. Langmuir 35 (2019) 14959-14966
Dewetting Rheology for Determining Viscoelastic Properties of Non-equilibrated Thin Polymer Films
Austine A. Mulama, Sivasurender Chandran, Konstantinos Roumpos, Andrew O. Oduor, and Günter Reiter. Macromolecules 52 (2019) 7894-7903
Relation between Charge Transport and the Number of Interconnected Lamellar Poly(3-hexylthiophene) Crystals
Binghua Wang, Jingbo Chen, Changyu Shen, Günter Reiter, Bin Zhang. Macromolecules 52 (2019) 6088-6096
Fully Isotactic Poly(p-methylstyrene): Precise Synthesis via Catalytic Polymerization and Crystallization Studies
Tianyu Wu, Luis Valencia, Thomas Pfohl, Barbara Heck, Günter Reiter, Pierre Lutz, Rolf Mülhaupt. Macromolecules 52 (2019) 4839-4846
Photoelectronic properties of composite films based on conductive polymer PIDT-BT and single-walled carbon nanotubes
Andrey N. Aleshin, Baode Zhang, Petr A. Aleshin, Vasily N. Petrov, Irina N. Trapeznikova, Günter Reiter, Janis Kleperis. SN Applied Sciences 1 (2019) 1101
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